Bi- and tri-nuclear ruthenium(II) complexes containing tetrapyridophenazine as a rigid bridging ligand
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 8,p. 885-886
- https://doi.org/10.1039/a709013g
Abstract
The rigid, aromatic bis-tridentate bridging ligand tetrapyrido[2,3-a:3′,2′-c:2″,3″-h:3″′,2″′-j]phenazine (tpp) allowed the preparation of linear, stable bi- and tri-nuclear complexes of ruthenium(II) exhibiting low energy Ru → tpp MLCT absorptions and a strong electronic coupling in the mixed-valence state.Keywords
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