A Convenient Route to Aryl Trifluoromethyl Sulfones by Fluoride-Catalyzed Cross-Coupling of Arenesulfonyl Fluorides with (Trifluoromethyl)trimethylsilane and (Trifluoromethyl)trimethylstannane
- 1 January 1990
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1990 (12) , 1151-1152
- https://doi.org/10.1055/s-1990-27121
Abstract
Trifluoromethylsulfonyl substituted aromatic compounds 3a-d are prepared from the corresponding sulfonyl fluorides 1a-d by reacting with (trifluoromethyl)trimethylsilane (or-stannane) in the presence of a base under mild conditions in high yields.Keywords
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