Isolation of some new tryptoquivaline-related metabolites from Aspergillus fumigatus.

Abstract
The structures of tryptoquivaline L, M and N were newly isolated from the fungus, A. fumigatus. Concomitantly, the previously proposed structures of tryptoquivaline, C and D, were revised. The exchange of the H on C-12 during epimerization of the dextrorotatory tryptoquivalines was demonstrated by a deuterium NMR spectral study.

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