Stereoselective induction of an axiel chirality by Suzuki cross coupling of tricarbonyl(arene)chromium complexes with arylboronic acids
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 2697-2698
- https://doi.org/10.1039/c39940002697
Abstract
Tricarbonyl(2,6-disubstituted-1-bromobenzene)chromium was treated with ortho-substituted phenylboronic acids in the presence of a palladium(0) catalyst to give mono-Cr(CO)3 complexes of biphenyl componds with a complementary axial chirality depending upon the nature of ortho-substituent of the phenylboronic acidsKeywords
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