Δ-Ni(phen)32+–montmorillonite as a template for asymmetric syntheses (phen = 1,10-phenanthroline)
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 119-120
- https://doi.org/10.1039/c39840000119
Abstract
Colloidal particles of Δ-Ni(phen)3 2+–montmorillonite(phen = 1,10-phenanthroline) act as asymmetric templates in the reactions (i) Co2+ with 1-(2-pyridylazo)-2-naphthol to from an optically active CoIIIcomplex and (ii)the reduction of benzil with NaBH4 to (S,S)-1,2-diphenylethane-1,2-diol.Keywords
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