Synthesis of polycyclic molecules via cascade radical carbocyclizations of dienynes: the first SnPh3 radical-mediated [2 + 2 + 2] formal cycloaddition of dodeca-1,6-dien-11-ynes
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2629-2630
- https://doi.org/10.1039/cc9960002629
Abstract
The dodeca-1,6-dien-11-ynes 1 and 5 give the polycyclic molecules 4 and 7, respectively, in the first known [2 + 2 + 2] cycloaddition reaction promoted by triphenyltin hydride, in a cascade free radical process.Keywords
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