Experimental and calculated electronic structure of gaseous CrO2F2 and CrO2Cl2
- 15 July 1975
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 63 (2) , 757-771
- https://doi.org/10.1063/1.431355
Abstract
The gas phase electronic absorption spectra of CrO2F2 and CrO2Cl2 have been measured in the visible, near ultraviolet regions. Interpretation has been made by comparison with a molecular orbital calculation for each molecule by the SCF-Xα-SW method. The calculated ground and excited states and observed electronic transitions correlate directly with those for the parent isoelectronic CrO2−4 and MnO−4 species.Keywords
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