First Steps Towards an Interchange Mechanism Scale for Substitution in Octahedral Transition Metal Am(m)ine Complexes
- 1 August 1994
- journal article
- research article
- Published by Taylor & Francis in Comments on Inorganic Chemistry
- Vol. 16 (4) , 229-242
- https://doi.org/10.1080/02603599408035861
Abstract
If the activation entropies ΔS∗) for a series of thermal or Hg2+−assisted chloride release aquation rates from chloroam(m)ine complexes are ranked, orders for the effect of the non-replaced ligands are obtained. These orders are within reasonable expectation for the extent of interchange that takes place as the reaction proceeds.Keywords
This publication has 17 references indexed in Scilit:
- Anionopentaaminecobalt(III) Complexes With Polyamine Ligands. XXVI. Spontaneous and Hg2+-Assisted Chloride Release Kinetics From Some CoCl(tacn)(diamine)2+ ComplexesAustralian Journal of Chemistry, 1993
- Molar volumes of coordination complexes in nonaqueous solution: correlation with computed van der Waals volumes, crystal unit cell volumes, and chargeInorganic Chemistry, 1992
- New Insights into the Mechanisms of Spontaneous and Base-Catalysed Substitution Reactions of the Inert Metal Amine ComplexesComments on Inorganic Chemistry, 1991
- Effect of geometric restraints on lability of acidoamine cobalt(III) complexesPure and Applied Chemistry, 1988
- Structural Characterization of trans‐[Cr(NH3)4(H2O)Cl]Cl2 and trans‐[Cr(NH3)4Cl2]lZeitschrift für anorganische und allgemeine Chemie, 1985
- Computer modeling of rare solvent exchangeThe Journal of Physical Chemistry, 1983
- Synthesis, acid hydrolysis, and Visible spectra of some bromopentakis(alkylamine)cobalt(III) complexesZeitschrift für anorganische und allgemeine Chemie, 1976
- Pressure Effects upon the Rates of Aquation of Halopentaamminechromium(III) Ions: Evidence for an Associative MechanismCanadian Journal of Chemistry, 1973
- The kinetics of the base hydrolysis of the iodo and nitratopentaaminecobalt(III) ionsJournal of Inorganic and Nuclear Chemistry, 1971
- Nature of the intermediate in unimolecular octahedral aquationInorganic Chemistry, 1968