Transition-metal nitrosyl compounds. Part VI. Mononitrosyltrichloromolybdenum, mononitrosyltrichlorotungsten, and some related derivatives
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 4,p. 508-510
- https://doi.org/10.1039/dt9720000508
Abstract
Nitrosyl chloride reacts with Mo2(CO)8Cl4 and W2(CO)8Cl4 to give the new mononitrosyl derivatives tentatively formulated as [Mo(NO)Cl3]n and [W(NO)Cl3]n together with small amounts of [Mo(NO)2Cl2]m and [W(NO)2Cl2]m. [Mo(NO)Cl3]n reacts with triphenylphosphine, triphenylphosphine oxide, 2,2′-bipyridyl, or NaS2CNR2 to give the mononitrosyl derivatives Mo(NO)Cl3(Ph3PO)2, Mo(NO)Cl3(bipy), or Mo(NO)(S2CNR2)3 which have been fully characterised.Keywords
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