Selectivity of the Oxidative Attack on a Model Ester Lubricant
- 1 January 1977
- journal article
- research article
- Published by Taylor & Francis in A S L E Transactions
- Vol. 20 (4) , 282-286
- https://doi.org/10.1080/05698197708982844
Abstract
The relative oxidative attack at the various carbon-hydrogen bonds of the model ester lubricant neopentyl hexanoate at temperatures 150–200 C was determined by GLC analysis of appropriate derivatives. Relative rates for single carbon-hydrogen bonds were: primary I,“normal” secondary 15, alpha-acyl secondary 2, and alpha-alcohol secondary 4. These results may furnish valuable insight in the development of more oxidatively stable esters for use in high-temperature jet engine lubricants.Keywords
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