Efficient Charge Separation in C60-Based Dyads: Triazolino[4‘,5‘:1,2][60]fullerenes
- 16 March 2000
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 65 (7) , 1978-1983
- https://doi.org/10.1021/jo991248d
Abstract
Triazoline[4,5][60]fullerenes are strong electron acceptors that form with tetrathiafulvalene (TTF), a novel type of donor−acceptor dyad exhibiting efficient improved electron-transfer dynamics. In particular, a rapid photoinduced intramolecular electron transfer, forming a charge-separated state, is followed by a slow charge recombination to generate the fullerene triplet excited state in moderate quantum yields.Keywords
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