Insertion of Isocyanides into the Palladium-Carbon Bond of Cyclopalladated Complexes
Open Access
- 1 November 1994
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 49 (11) , 1494-1498
- https://doi.org/10.1515/znb-1994-1107
Abstract
Insertion of isocyanides into the Pd-C bond has been observed in the reactions of PdBr[C6H3(CH2NMe2)2-2,6] with isocyanides CNR which give the complexes PdBr[C(=NR)C6H3(CH2NMe2)2-2,6-C̲,N̲](CNR) (2a-d). An imino bridged complex 5 is formed on heating the imino complex PdCl[C(=NCH2CO2Et){C6H4(CH2NMe2)-2}](CNCH2CO2Et). The structures of 2c (R = nBu) and 5 have been determined by X-ray crystallography.Keywords
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