Electrocatalytic reduction of CO2 based on polypyridyl complexes of rhodium and ruthenium
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 796-797
- https://doi.org/10.1039/c39850000796
Abstract
Electrocatalytic reduction of CO2 to either CO or formate ion in MeCN solution has been shown to occur using precursor complexes such as Ru(trpy)(dppene)Cl+ or cis-Rh(bpy)2(TFMS)2 +[trpy = 2,2′,2″-terpyridine; dppene =cis-1,2-bis(diphenylphosphino)ethylene; bpy = 2,2′-bipyridine; TFMS = trifluoromethanesulphonate anion].Keywords
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