Inorganic six-membered ring inversion. The inversion barrier in the tris(pentasulphane-1,5-diyl)platinate(IV) anion
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 332-333
- https://doi.org/10.1039/c39820000332
Abstract
195 Pt N.m.r. studies of the ring inversion in the tris(pentasulphane-1,5-diyl)platinate(IV) anion reveal two conformations separated by a barrier(ΔG‡ at 273 K) of 50.5 ± 1.3 kJ mol–1.Keywords
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