Efficient homogeneous photochemical water gas shift reaction catalysed under extremely mild conditions by novel iridium(III) complexes: [(η⁵-Me₅C₅)Ir(bpy)Cl]⁺, [(η⁵-Me₅C₅)Ir(bpy)H]⁺, and [(η⁵-Me₅C₅)Ir(phen)Cl]⁺(bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline)

1 January 1988

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 1,p. 16-17
https://doi.org/10.1039/c39880000016

Abstract

The title compounds are shown to be active catalysts for the light-driven water gas shift reaction with turnover numbers up to 10 h^–1; the iridium hydride species exhibits strong luminescence in solution at room temperature.

Keywords

WATER GAS SHIFT

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Efficient homogeneous photochemical water gas shift reaction catalysed under extremely mild conditions by novel iridium(III) complexes: [(η5-Me5C5)Ir(bpy)Cl]+, [(η5-Me5C5)Ir(bpy)H]+, and [(η5-Me5C5)Ir(phen)Cl]+(bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline)

Abstract

Keywords

Efficient homogeneous photochemical water gas shift reaction catalysed under extremely mild conditions by novel iridium(III) complexes: [(η⁵-Me₅C₅)Ir(bpy)Cl]⁺, [(η⁵-Me₅C₅)Ir(bpy)H]⁺, and [(η⁵-Me₅C₅)Ir(phen)Cl]⁺(bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline)