Synthesis and Characterization of the Poly-(2-Methoxycyanurate) of 1,1?-Bis-(4-Hydroxyphenyl)-cyclohexane
- 1 November 1985
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 22 (11) , 1495-1508
- https://doi.org/10.1080/00222338508063350
Abstract
The poly-(2-methoxycyanurate) of l, l′-bis-(4-hydroxyphenyl)-cyclohexane (PMCBC) was synthesized by the interfacial poly-condensation technique. The polymer was fractionated by preparative gel permeation chromatography (GPC). The fractions were characterized by viscometry, osmometry, and GPC techniques. The viscosity-molecular weight relationship was established in pure solvent and in different binary solvent mixtures. The unperturbed dimensions, (〈R2〉0/M)1/2, and the solvent-polymer interaction parameter, B, were computed by applying the two-parameter theories of the excluded-volume effect.Keywords
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