Chemistry of the Group 1B metals. X. Reactions between silver arylacetylides and some rhodium(I) and iridium(I) complexes

Publisher Website
Google Scholar
Abstract
Reactions between AgC2Ar (Ar = Ph or C6F5) and RhCl(PPh3)3 or IrCl(CO)(PPh3)2 have given hexanuclear heteroatom cluster compounds M2Ag4(C2Ar)8(PPh3)2 (M = Rh or Ir), and the zwitterionic complexes {[Ag(PPh3)]+ [M(C2C6F5)4(PPh3)2]-} and {[Ag(PPh3)]2+ [Rh(C2C6F5)5(PPh3)] 2-}.The structures of these complexes are described and discussed, together with possible reactions by which they may be formed.