Production and Reaction of Atomic Fluorine in Solids. Vibrational and Electronic Spectra of the Free Radical HNF
- 1 January 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 46 (1) , 184-191
- https://doi.org/10.1063/1.1840369
Abstract
The species H14NF, H15NF, and D14NF have been produced in an argon matrix at 14°K by the reaction of photolytically produced atomic fluorine with NH. Sufficient concentrations of these species have been obtained for direct detection of two vibrational fundamentals, appearing at 1000 and 1432 cm−1 for H14NF, as well as of an electronic transition between 3900 and 5000 Å involving a progression in the upper‐state bending frequency. Force constants and thermodynamic properties have been derived for HNF. Other species observed in these experiments include NF, NF2, and HNF2. Evidence is presented indicating that the hydrogen atom can be abstracted from HN3 by atomic fluorine.Keywords
This publication has 22 references indexed in Scilit:
- THE 2 700 Å BANDS OF THE N3 MOLECULECanadian Journal of Physics, 1965
- Infrared Spectra of NF, NCl, and NBrThe Journal of Chemical Physics, 1964
- Infrared Spectrum and Thermodynamic Functions of the NF2 RadicalThe Journal of Chemical Physics, 1962
- The Tetrafluorohydrazine-Difluoroamino Radical Equilibrium1Journal of the American Chemical Society, 1961
- THE 0–0 AND 1–0 BANDS OF THE A(3Πi)–X(3Σ−) SYSTEM OF NHCanadian Journal of Physics, 1959
- The detection of free radicals in the high intensity photolysis of hydrogen azideProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1956
- The Absorption Spectrum of Fluorine1Journal of the American Chemical Society, 1956
- Infrared and Raman Spectra of Nitrogen TrifluorideThe Journal of Chemical Physics, 1955
- Experimental Performance of Curved SlitsJournal of the Optical Society of America, 1953
- A Small Plane Grating MonochromatorJournal of the Optical Society of America, 1952