Polymer-supported formamides as reusable organocatalysts for allylation of aldehydes with allyltrichlorosilane
- 20 December 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 2,p. 192-193
- https://doi.org/10.1039/b210826g
Abstract
New types of polymer-supported formamides have been synthesized from chloromethylated resins and formamides; it was found that the polymers worked well as organocatalysts in the allylation of aldehydes with allyltrichlorosilane to afford homoallylic alcohols in high yields; the polymers were easily recovered and reused several times without loss of activity.Keywords
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