Pentafluorophenyl nitrene: a matrix isolated aryl nitrene thet does not undergo ring expansion

Abstract
Photolysis of pentafluorophenyl azide or pentafluorophenyl Isocyanate in low-temperature matrices gives pentafluorophenyl nitrene which, in the presence of CO, may react photochemically but not thermally to give the isocyanate.

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