Dielectric properties of charge-transfer complexes involving non-polar donors and acceptors
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 66, 92-98
- https://doi.org/10.1039/tf9706600092
Abstract
The dielectric relaxation times of charge-transfer complexes formed between the acceptors tetracyanoethylene, tetrachloro-p-benzoquinone, 2,5-dichloro-p-benzoquinone, p-benzoquinone and the donors, mesitylene and dioxan are reported. The relaxation times are interpreted as a measure of the life-time of the complex. The importance of electrostatic interaction in the stabilization of the ground state of the π-π complexes is emphasized.Keywords
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