C−C Bond Formation via Double C−H Functionalization: Aerobic Oxidative Coupling as a Method for Synthesizing Heterocoupled Biaryls
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- 7 July 2007
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 9 (16) , 3137-3139
- https://doi.org/10.1021/ol071308z
Abstract
The aerobic oxidative coupling of arenes such as benzofuran and N-substituted indoles with benzene and derivatives thereof is described. The reaction is shown to take place in both inter- and intramolecular scenarios.Keywords
This publication has 17 references indexed in Scilit:
- Intermolecular Cross-Coupling of Simple Arenes via C−H Activation by Tuning Concentrations of Arenes and TFAOrganometallics, 2006
- Palladium-Catalyzed C−H Homocoupling of Bromothiophene Derivatives and Synthetic Application to Well-Defined OligothiophenesJournal of the American Chemical Society, 2006
- Catalytic Intermolecular Direct Arylation of PerfluorobenzenesJournal of the American Chemical Society, 2006
- Room Temperature Palladium-Catalyzed 2-Arylation of IndolesJournal of the American Chemical Society, 2006
- Computational Study of the Mechanism of Cyclometalation by Palladium AcetateJournal of the American Chemical Society, 2005
- Oxidative Coupling of Benzenes with α,β-Unsaturated Aldehydes by the Pd(OAc)2/Molybdovanadophosphoric Acid/O2 SystemThe Journal of Organic Chemistry, 2005
- Direct Palladium-Catalyzed C-2 and C-3 Arylation of Indoles: A Mechanistic Rationale for RegioselectivityJournal of the American Chemical Society, 2005
- Palladium‐Catalyzed Intermolecular Alkenylation of Indoles by Solvent‐Controlled Regioselective C-H FunctionalizationAngewandte Chemie International Edition in English, 2005
- The Myth of Cyanide Always Being a Strong‐Field Ligand: Synthesis and Structural Characterization of Homoleptic S=2 Pentacyanochromate(II), [CrII(CN)5]3−, and Nonacyanodichromate(II), [${{\rm Cr}{{{\rm II}\hfill \atop 2\hfill}}}$(CN)9]5−Angewandte Chemie International Edition in English, 2005
- Oxidative coupling of 5-membered heterocycles catalyzed by a Pd(II)-heteropolyacid system in dimethylformamideReaction Kinetics, Mechanisms and Catalysis, 1978