Transition-metal-catalysed reactions of diazoesters. Insertion into C–H bonds of paraffins by carbenoids
- 1 January 1981
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 688-689
- https://doi.org/10.1039/c39810000688
Abstract
Rhodium(II) carboxylates of perfluoroacids are very efficient catalysts for promoting the insertion of carbenes (carbenoids)(generated from diazoesters) into the C–H bonds of alkanes with selectivites which differ from those observed in typical free-crbene processes.Keywords
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