Reactions of permethylmetallocene alkyne complexes of titanium and zirconium with tris(perfluorophenyl)borane
- 1 January 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 3,p. 241-242
- https://doi.org/10.1039/a908591b
Abstract
Functionalization of the pentamethylcyclopentadienyl ligands by an electrophilic substitution of hydrogen atoms by [B(C6F5)3] is observed at the Cp* ligands of the alkyne complexes [Cp*2M(η2-PhC2SiMe3], connnected with (M = Ti, formation of 1) or without (M = Zr, formation of 2) loss of the alkyne and molecular hydrogen.Keywords
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