Evidence for octa-co-ordination in alcohol–lanthanide-shift-reagent complexes and its implications in the search for the geometric factor govering observed shifts
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1193-1194
- https://doi.org/10.1039/c39720001193
Abstract
The c.d. spectral changes induced in the euroium 5F0→5D1 band (524 nm) of the shift reagent, Eu(fod)3, on complexing optically active alcohols indicate that the major species present at standard n.m.r. concentrations and ratios is octa-co-ordinated, Eu(fod)3(ROH)2.Keywords
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