Direct and Selective N-Monoalkynylation and N-Monoalkenylation of Anilines with Alky(e)nyl Methanesulfonates Using Methylmagnesium Bromide as a Base
- 1 May 1997
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1997 (05) , 533-535
- https://doi.org/10.1055/s-1997-1225
Abstract
Several anilines were directly N-monoalkynylated and N-monoalkenylated with alkynyl methanesulfonates and alkenyl methanesulfonates, respectively, using methylmagnesium bromide as a base in good yields with high selectivities.Keywords
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