A new type of decaosmium cluster geometry: the synthesis and X-ray structure analysis of Os10(S)2(CO)23
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 595-597
- https://doi.org/10.1039/c39840000595
Abstract
Pyrolysis of Os3(CO)12 with elemental sulphur gives a range of clusters including Os3(S)2(CO)9, Os5S(CO)15, Os6(CO)18, Os7(S)2(CO)20, and Os10(S)2(CO)23(1); X-ray analysis shows that (1) has a new type of Os10 metal core geometry.Keywords
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