Regioselective Zirconium-Mediated Cross Coupling of N-Methyl-N-propargyl Aniline and Alkenes
Open Access
- 1 March 1995
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 50 (3) , 312-314
- https://doi.org/10.1515/znb-1995-0302
Abstract
N-(2-bromoallyl)-N-methylaniline 1 is easily converted into the propargylamine-zirconocene complex 3 via loss of methane from 2-[zirconocene(methyl)]allyl amine 2. Regioselective insertion reactions with alkenes and benzophenone afford, after iodinolysis, products 4 -10.Keywords
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