CORRELATION OF THE RATE CONSTANTS OF PROPAGATION WITH THE STRUCTURES OF MONOMERS AND ACTIVE CENTERS IN CHAIN-GROWTH POLYMERIZATION
- 1 February 1986
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science, Part C: Polymer Reviews
- Vol. 26 (1) , 1-32
- https://doi.org/10.1080/07366578608081967
Abstract
Structure-reactivity correlation is one of the most fundamental problems in chemistry. In organic chemistry the influence of the structure of substituents on the rate and equilibrium constants of chemical reactions was first quantitatively established and presented in the form of the well-known Hammett equation.Keywords
This publication has 43 references indexed in Scilit:
- Model copolymerization reactions. Direct observation of a "penultimate effect" in a model styrene-acrylonitrile copolymerizationJournal of the American Chemical Society, 1985
- Macroions and Macroion Pairs in the Anionic Polymerization of β-Propiolactone (β-PL)Macromolecules, 1980
- Hammett Relations in Anionic Polymerization. Reaction of Polystyrylakali Salts with Disubstituted 1,1-DiphenylethylenesMacromolecules, 1977
- 13C Nuclear Magnetic Resonance Studies on the Polymerization of Cyclic EthersMacromolecules, 1975
- The macroester ⇄ macroion equilibrium in the cationic polymerization of THF observed directly by 300 MHz1 H NMRJournal of Polymer Science: Polymer Chemistry Edition, 1974
- Stereochemical studies. LI. Effect of ring size on the rates of quaternization of the N-methylazacycloalkanesCollection of Czechoslovak Chemical Communications, 1968
- Correlation of cationic copolymerization parameters of cyclic ethers, formals, and estersJournal of Polymer Science Part A-1: Polymer Chemistry, 1966
- Nucleophilic ReactivityAnnual Review of Physical Chemistry, 1963
- Ionic Polymerization. Copolymerization of Nuclear and Side-chain Alkyl-substituted Styrene Monomers1Journal of the American Chemical Society, 1958
- The Effect of Structure upon the Reactions of Organic Compounds. Benzene DerivativesJournal of the American Chemical Society, 1937