Dicopper(II) and dicopper(III) complexes with a double-ring octa-aza macrocycle
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1166-1167
- https://doi.org/10.1039/c39820001166
Abstract
The novel double-ring octa-aza molecule (2) incorporates two copper(II) ions in aqueous solution with simultaneous release of four protons; the resulting dicopper(II) complex shows a weak metal–metal interaction and is easily oxidized to the trivalent state by two consecutive one-electron steps separated by 110 mV.Keywords
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