Infrared and Raman spectra of di-µ-halogeno-bis[dihalogenocadmate(II)] anions
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 19,p. 1914-1917
- https://doi.org/10.1039/dt9770001914
Abstract
The salts [NR4]x[(CdX3)x](R = Prn or longer n-alkyl; X = Cl, Br, or I) are shown by i.r. and Raman spectroscopy to contain the halide-bridged dimeric anions [Cd2X6]2– both in the solid state and when dissolved in non-complexing solvents. Recent conclusions on the nature of the mixed-halide systems [NPrn 4]x[(CdX2Y)x] are shown to be questionable. Previous assignments for the anions [CdX4]2– have been augmented from studies on [NR4]2[CdX4].Keywords
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