Crystal and molecular structure of a novel mixed-spin binuclear nickel(II) complex with N,N′,N″,N‴-tetrakis(2-aminoethyl)-1,4,8,11-tetra-azacyclotetradecane
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 5,p. 1261-1262
- https://doi.org/10.1039/dt9870001261
Abstract
The crystal structure of [Ni2(taec)Cl]Cl3·H2O was determined by the single-crystal X-ray diffraction method, where taec is N,N′,N″,N‴-tetrakis(2-aminoethyl)-1,4,8,11-tetra-azacyclotetradecane. The [Ni2(taec)Cl]3+ cation has a novel binuclear structure in which one of the nickel ions is co-ordinated by a square-planar N4 donor set and the other by a distorted square-pyramidal N4Cl donor set.Keywords
This publication has 0 references indexed in Scilit: