THE SYNTHESIS OF 3-O-[(BENZYLTHIO)CARBONYL]-β-D-GLUCOPYRANOSE AND METHYL 2,4,6-TRI-O-BENZOYL-α AND β-D-GLUCOPYRANOSIDES
Open Access
- 1 November 1964
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 42 (11) , 2560-2567
- https://doi.org/10.1139/v64-374
Abstract
The discovery that the (benzylthio)carbonyl group is stable in concentrated hydrochloric acid has permitted the removal in that medium of isopropylidene blocking groups from 3-O-[(benzylthio)carbonyl]-1,2;5,6-di-O-isopropylidene-α-D-glucofuranose to furnish crystalline 3-O-[(benzylthio)carbonyl]-β-D-glucopyranose. Benzoylation of the latter provided a derivative which has made possible the synthesis of methyl 2,4,6-tri-O-benzoyl-α and β-D-glucopyranosides.Keywords
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