Bis-π-cyclopentadienyl complexes of molybdenum and tungsten containing trihalogenostannyl-, oxo-, sulphato-, and thiosulphato-ligands
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 14,p. 1445-1447
- https://doi.org/10.1039/dt9720001445
Abstract
The complexes (π-C5H5)2M(SnX3)X, where M = Mo or W and X = Cl or Br are described. They react with chlorine or bromine respectively forming the salts [(π-C5H5)2MX2]+SnX3 –. The complexes (π-C5H5)2MO (M = Mo or W). (π-C5H5)2MoSO4, and (π-C5H5)2MoS2O3 have also been prepared.Keywords
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