Synthesis of Aryliodides from Diazonium Tetrafluoroborate in Dimethylsulfoxide
- 1 January 1981
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 11 (8) , 639-642
- https://doi.org/10.1080/00397918108063637
Abstract
One of the best methods for the introduction of iodine in the aromatic ring, is the reaction of arenediazonium salts with iodine ions in water1, for which a free radical mechanism was proposed2. Although the yields are generally good, numerous attempts were made to improve the method and to simplify the isolation procedure.Keywords
This publication has 3 references indexed in Scilit:
- Steric and polar effects in free-radical reactions. - An unusual type of azocoupling by free radical decomposition of diazonium saltsTetrahedron Letters, 1980
- Crown-cation complex effects. IX. A phase transfer catalytic synthesis of bromo- and iodoarenesTetrahedron Letters, 1977
- Electron transfer mechanism of aromatic 'nucleophilic' substitutionAustralian Journal of Chemistry, 1972