Selective Favorskii rearrangment of α,α,α′-dibromochlorocycloalkanones of medium ring size
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2471-2474
- https://doi.org/10.1039/p19830002471
Abstract
α,α,α′-Dibromochlorocycloalkanones of medium ring size have been prepared by treatment of chlorocycloalkanones with bromine and were separated by chromatorgraphy and then submitted to Favorskii reaction. The stereoisomeric reaction products have in each case been evaluated by gas chromatography and the selectivity of bromide elimination deduced.Keywords
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