K10M4Sn4S17 (M = Mn, Fe, Co, Zn): Soluble Quaternary Sulfides with the Discrete [M4Sn4S17]10- Supertetrahedral Clusters
- 19 July 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 42 (17) , 5052-5054
- https://doi.org/10.1021/ic034600l
Abstract
Four cubic compounds are reported that contain the supertetrahedral cluster [M4Sn4S17]10- where M = Mn, Fe, Co, Zn. The cluster features a central quadruply bridging sulfide ion (μ4-S) that holds together four divalent M atoms in a tetrahedral arrangement. This core is capped with four tridentate [SnS4]4- fragments to complete the structure.Keywords
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