Asymmetric Diels–Alder reactions of sulphinyl-activated dienophiles obtained via a self-induced chiral oxidation
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 878-880
- https://doi.org/10.1039/c39850000878
Abstract
The Diels–Alder cycloaddition of activated vinyl sulphoxides (1), that are readily obtained by a self-induced chiral oxidation, proceeds highly diastereoselectively to form the corresponding cycloadducts (4) that can be converted into 2-substituted norbornadienes(5) of high enantiomeric purity.Keywords
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