Differential use of the pyranoside ring for stereocontrolled routes to triquinanes: silphinene and silphiperfolene skeleta
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1440-1443
- https://doi.org/10.1039/c39900001440
Abstract
The use of the pyranosidodiquinane 7 as a key intermediate for constructing the skeleta of 1 and 2 involving a procedure in which all of the stereochemistry is established at the level of 7 before the sugar residue is utilized to obtain this ring.Keywords
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