Fluoride ion mediated peterson alkenation of bis(trimethylsilyl)methylimines: a novel synthesis of 2-aza-1,3-dienes and N-vinyl-β-lactams
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 72-74
- https://doi.org/10.1039/c39890000072
Abstract
The formation of bis(trimethylsily)methylimines and their transformation into aza-1,3-dienes by means of a fluoride-induced catalytic Peterson alkenation is reported; when the procedure was applied to N-[bis(trimethylsilyl)methyl]-azetidin-2-ones, a wide range of N-vinyl derivatives were obtained in high yields.Keywords
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