Detection of surface (∼1 μm) impurity phases in high T c superconductors

Abstract
We show that thermally stimulated luminescence is an important method for detecting insulating impurity phases that commonly occur in high Tc superconductors. The technique is sensitive to impurity phases at 2O3, Y2BaCuO5, YBa2Cu3O6.2, BaCO3, Ba3CuO4, BaCuO2, and YBa2Cu3Ox (x≊7) were investigated. All but the high quality sintered pellets of YBa2Cu3Ox exhibited relatively intense luminescence. The absence of luminescence, and thus of insulating phases, is correlated with low values of rf surface resistance.