Novel cage compounds from inter-intra-molecular Diels–Alder reactions of 1,2,4-triazines with cyclo-octa-1,5-diene
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1482-1483
- https://doi.org/10.1039/c39880001482
Abstract
1,2,4-Triazines with electron-withdrawing substituents at the three position react with cyclo-octa-1,5-diene by intermolecular Diels–Alder addition followed by elimination of nitrogen; the 2-azadiene so formed then undergoes an intramolecular Diels–Alder reaction producing novel cage compounds.Keywords
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