Sterically protected hemins with electronegative substituents: efficient catalysts for hydroxylation and epoxidation
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 279-280
- https://doi.org/10.1039/c39840000279
Abstract
Meso-tetra(2,6-dichlorophenyl)porphinatoiron(III)chloride and meso-tetra(pentachlorophenyl)porphinatioiron(III)chloride, which resist µ-oxo dimmer formation and oxidative destruction, are found to be unusually efficient catalysts for high-turnover, high-yield alkene epoxidation and alkane hydroxylation.Keywords
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