Thiocarboxamido complexes of manganese and molybdenum
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 804-805
- https://doi.org/10.1039/c39720000804
Abstract
Reaction of CpMo(CO)3 – and ClCSNMe2 yields CpMo(CO)2CSNMe2 which gives [CpMo(CO)2C(SMe)NMe2]+(isolated eventually as the PF6 – salt) with [Me3O]BF4; the same reactions are reported with Mn(CO)4PPh3 –; the structures of these complexes are believed to involve the C–S group as a bidentate three electron donor.Keywords
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