Force Constants, Infrared Spectrum, and Thermodynamic Properties of TiCl4
- 1 September 1955
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 23 (9) , 1700-1702
- https://doi.org/10.1063/1.1742414
Abstract
The spectrum of gaseous titanium tetrachloride was obtained in the rock salt and potassium bromide regions of the infrared. The thermodynamic functions Cp0, S0, and — (F0—E00)/T were calculated. The orbital valence force field constants were computed, and lead to the conclusion that hybridization changes may be significant in the F2-vibrations.Keywords
This publication has 5 references indexed in Scilit:
- Molecular force fields. Part VI.—distortions of bond-forming orbitals and the effect on molecular vibrationsTransactions of the Faraday Society, 1949
- Molecular force fields. Part IV.—The application of the orbital valency force field to tetrahedral halidesTransactions of the Faraday Society, 1948
- Molecular force fields. II. The force field of the tetrahalides of the Group IV elementsTransactions of the Faraday Society, 1948
- Étude d'ensemble des spectres Raman des molécules pentatomiques tétraédriques. IJournal de Physique et le Radium, 1946
- The investigation by electron diffraction of the structures of some tetrahalidesTransactions of the Faraday Society, 1941