Reaction of chlorosulphonyl isocyanate with ethyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside: a reinvestigation
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 7,p. 626-629
- https://doi.org/10.1039/p19750000626
Abstract
The minor products of the reaction of chlorosulphonyl isocyanate with a hex-2-enopyranoside in ether and in acetonitrile include a 3-alkoxycarbonylamino-3-deoxy-allal, 2-(D-glycero-1,2-diacetoxyethyl)furan, two hex-2-enopyranosylamines, and two C–C linked disaccharide derivatives. Reaction mechanisms are discussed.Keywords
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