Normal coordinate analysis of titanium(IV) halide: monoethylenediamine complexes

15 January 1969

journal article
Published by Canadian Science Publishing in Canadian Journal of Chemistry

Vol. 47 (2) , 167-169
https://doi.org/10.1139/v69-022

Abstract

A partial normal coordinate analysis was performed for the Ti(en)X₄ complexes, assuming gauche configuration of the ligand and overall symmetry of C₂ for the complex. Comparison of the calculated frequencies with the available experimental data supports the assumption of the chelate structure for the complexes and also confirms the previous assignments for the Ti—N stretching frequencies. Some new assignments are proposed in the 900–300 cm⁻¹ region.

Keywords

STRUCTURE
EXPERIMENTAL
CHELATE
SYMMETRY
ASSIGNMENTS
HALIDE
COORDINATE ANALYSIS
MONOETHYLENEDIAMINE

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