Chemistry of 1,2,4-trioxanes. Formation of 1,2-diol monoesters
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1783-1784
- https://doi.org/10.1039/c39850001783
Abstract
1,2,4-Trioxanes bearing a hydrogen substituent at the C-3 position when treated with trithylamine undergo scission of the oxygen-oxygen bond to give the corresponding 1,2-diol monoesters in high yields; similar treatment of a bridged 1,2,4-trioxane afforded the related γ-hydroxy-δ-lactone and its isomeric spirocyclic δ-lactone in 90% yield.Keywords
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