Variable dimensionality in atoms and its effect on the ground state of the helium isoelectronic sequence
- 1 January 1975
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 11 (1) , 42-53
- https://doi.org/10.1103/physreva.11.42
Abstract
We calculate binding energies for heliumlike ions of variable dimensionality () with the wave functions and . The binding energy decreases with increasing . Functions and predict "critical binding dimensionalities" at , respectively, above which there is no binding in the hydride anion. The exact ground-state binding energy at is shown to be equal to that of the doubly excited state into in three dimensions. By "dimensionality scaling" of atomic units the atom is transformed the -function model for which exact energies are known. In the infinite dimensional limit, function predicts no exchange contribution to binding for nuclear charge , with only for .
Keywords
This publication has 17 references indexed in Scilit:
- Role of electron correlation in determining the binding limit for two-electron atomsPhysical Review A, 1974
- Nonlinear variational study of perturbation theory for atoms and ionsPhysical Review A, 1974
- Feynman-Graph Expansion for Critical ExponentsPhysical Review Letters, 1972
- Critical Exponents in 3.99 DimensionsPhysical Review Letters, 1972
- Solution of the Delta Function Model for Heliumlike IonsThe Journal of Chemical Physics, 1971
- Ground-State Energy of Two-Electron AtomsThe Journal of Chemical Physics, 1966
- Potential scattering for complex energy and angular momentumIl Nuovo Cimento (1869-1876), 1962
- Some Remarks on the Negative Hydrogen Ion and its Absorption Coefficient.The Astrophysical Journal, 1944
- The Theory and Calculation of Screening ConstantsPhysical Review B, 1930
- Neue Berechnung der Energie des Heliums im Grundzustande, sowie des tiefsten Terms von Ortho-HeliumThe European Physical Journal A, 1929