Large-Scale Separation of K-frac and REEP-frac in the Source Regions of Apollo Impact-Melt Breccias, and a Revised Estimate of the KREEP Composition

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Abstract
Mafic impact-melt breccias (IMB) from the Apollo landing sites—particularly Apollo 14, Apollo 15, Apollo 16, and Apollo 17—are abundant and form compositionally distinct groups. These groups exhibit a range of major-element compositions and incompatible-element enrichments. Although concentrations of incompatible elements span a significant range, inter-element ratios vary little and have been used in the past to infer a common KREEP component (KREEP = rich in potassium, rare-earth elements, phosphorus, and other alkali and high-field-strength elements). On the basis of an extensive, high-precision data set for melt-breccia groups from different Apollo landing sites, variations in trace-element signatures of the mafic impact-melt breccias reflect significant differences in KREEP components of source regions. These differences are consistent with variable enrichment or depletion of source regions in those trace elements that fractionated during the latest stages of residual-melt evolution and are more or less related to “lunar granite.” Compared to other sites, the source region of Apollo 14 impact melts had an excess of the elements that are concentrated in lunar granite, suggesting either than this source region was enriched in such a component (K-frac) or that it lost a corresponding mafic component (REEP-frac). Because these are impact-melt breccias formed in large (probably basin) impacts, the indicated geochemical separations must have occurred on a broad scale. Variations in the incompatible-element concentrations of the IMB groups reported in this paper are used to calculate a revised KREEP incompatible-element composition. On the basis of several extremely enriched lunar samples that retain the incompatible elements in KREEP-like ratios, the KREEP composition is extended to a level of 300 ppm La, or about three times the concentration of high-potassium KREEP as estimated by Warren (1989).